The application of thickeners in water-based architectural coatings
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Time:2023-08-09 09:22
Functions and Classification of Thickeners in Water-Based Architectural Coatings
Functions of Thickeners
Thickeners are one of the essential raw materials in water-based coatings, playing an indispensable role. Thickeners increase the viscosity of water-based coatings, slow down the sedimentation rate of pigments and fillers, maintain the looseness of pigments and fillers, prevent hard settling of pigments in the coating, allow for easy and even mixing of the coating, and ensure storage stability.
Some thickeners, when added to water-based coatings, can impart thixotropy, making the coatings easy to brush during application while reducing sagging and ensuring the appearance and quality of the coating. Special thickeners may also be added to achieve special coating patterns or textures.
Classification of Thickeners
Thickeners used in water-based architectural coatings can be classified into polysaccharide, polyacrylate, polyurethane, and inorganic types according to their chemical composition. These four types of thickeners are also the most common types used in coatings.
· Polysaccharide thickeners, including modified cellulose, xanthan gum, and guar gum. Cellulose is usually powdery; after dissolving in water, its hydroxyl groups associate with water to form a high-viscosity transparent liquid.
· Polyacrylate thickeners, also known as alkali-swellable thickeners, because they require alkalization to thicken. They can be divided into two categories: associative (HASE) and non-associative (ASE). Before use, acrylic thickeners are low-viscosity milky white emulsions; when encountering alkaline pH regulators, they form high-viscosity transparent liquids.
· Polyurethane thickeners, abbreviated as HEUR, are hydrophobic group-modified ethoxy polyurethane water-soluble polymers. Polyurethane thickeners themselves are low-viscosity transparent or translucent liquids; they need to associate with polymer emulsion particles to exhibit a thickening effect.
· Inorganic thickeners such as sodium-based bentonite, palygorskite, and silicon dioxide. Inorganic thickeners exhibit a thickening effect due to hydrogen bond association between particles.